A N-functionalized Tetranuclear Copper Complex with Catalytic Potential

【作者】 刘杰； Jin-Min Liu； Xu Jing； Li-Jin Li； Jian-Long Du；

【Author】 Jie Liu;Jin-Min Liu;Xu Jing;Li-Jin Li;Jian-Long Du;College of Chemistry & Environmental Science,Hebei University;

【机构】 河北大学； College of Chemistry & Environmental Science,Hebei University；

【摘要】 As a new porous material,metal-organic frameworks（MOFs） have attracted the attention of researchers.MOFs have structural diversity and adjustability,which facilitates the modification of their components using various catalytic sites.Fujita et.al.first used a metal site for catalytic reaction and they used Cd（4,4’-bpy）₂（NO₃）₂ to catalyzing the silylation reaction of acetaldehyde.¹ Ikuno et.al.synthesized Cu-NU-1000,which could catalytic the catalytic oxidation of methane to methanol under mild reaction condition.² In our work,compound 1 was synthesized by Suzuki coupling reaction based on carbazole.A new tetranuclear complex with Cu²⁺ions as the metal center was synthesized by hydrothermal method.Its catalytic properties is undergoing.更多还原

【Abstract】 As a new porous material,metal-organic frameworks（MOFs） have attracted the attention of researchers.MOFs have structural diversity and adjustability,which facilitates the modification of their components using various catalytic sites.Fujita et.al.first used a metal site for catalytic reaction and they used Cd（4,4’-bpy）₂（NO₃）₂ to catalyzing the silylation reaction of acetaldehyde.¹ Ikuno et.al.synthesized Cu-NU-1000,which could catalytic the catalytic oxidation of methane to methanol under mild reaction condition.² In our work,compound 1 was synthesized by Suzuki coupling reaction based on carbazole.A new tetranuclear complex with Cu²⁺ions as the metal center was synthesized by hydrothermal method.Its catalytic properties is undergoing.更多还原