【作者】 张建玲；

【Author】 Jianling Zhang;CAS Key Laboratory of Colloid,Interface and Chemical Thermodynamics,Institute of Chemistry,Chinese Academy of Sciences;

【机构】 胶体、界面与化学热力学院重点实验室,中国科学院化学研究所；

【摘要】 有序组装体的构筑、结构与功能调控是具有重要理论和实际意义的课题。有序组装一般在溶剂中进行,溶剂的组成和性质对有序组装体的形成及其结构调控具有重要的影响。我们针对一些重要的功能材料和化学反应,设计了一系列具有特殊结构和性质的溶剂体系,如超临界流体、离子液体、超临界二氧化碳/水、超临界二氧化碳/离子液体、离子液体/水等,通过结构基元和溶剂间相互作用研究、多组分协同效应研究等,创制了一系列新型有序组装体,揭示了溶剂性质对有序组装体形成和结构调控的规律和机理,利用这些新型组装体实现了材料可控合成和高效化学反应[1-12]。更多还原

【Abstract】 To construct novel kinds of ordered assemblies and tune their properties and structures are of great importance. Self-assembling usually proceeds in solvent, of which the composition and property have an important influence on the formation of ordered assembly and its structural regulation. We designed a series of solvent systems with unique compositions and properties including supercritical fluid, ionic liquid, supercritical CO2/ionic liquid, supercritical CO2/water and ionic liquid/water, etc. Various kinds of novel ordered assemblies were formed and their properties and structures can be easily tuned by controlling the solvent properties. These assemblies have been utilized in material synthesis and chemical reaction.更多还原