Ionic Liquid Templated Synthesis of New Silver Iodides

【作者】 宋丹娜； 廖水娇； 张仁春；

【Author】 Dan-Na Song;Shui-Jiao Liao;Ren-Chun Zhang;Henan Province Key Laboratory of New Optoelectronic Functional Materials, College of Chemistry and Chemical Engineering, Anyang Normal University;College of Basic Sciences, Huazhong Agricultural University;

【机构】 Henan Province Key Laboratory of New Optoelectronic Functional Materials, College of Chemistry and Chemical Engineering, Anyang Normal University； College of Basic Sciences, Huazhong Agricultural University；

【摘要】 Metal halides have attracted increasing attention because of their diverse structures and fascinating properties,such as porosity,fluorescence,semi-conductivity,nonlinear optical,thermochromism,photochromism,and effective visible optical catalytic properties.Ionic liquids consisting of pure ionic compositions,not only can afford ionic reaction medium,but also can provide designable template to aid the formation of new structures.~1 In this work,a series of Ag-I compounds were synthesized via the solvothermal reaction of AgI and ionic liquids.Systematic research reveals that ionic liquids are critical for the synthesis.Particularly,the structures are sensitive to the variation of the substitution group from C1 to C4.~2 While,the structures are unsensitive to the variation of the substitution group from C4 to C6.更多还原

【Abstract】 Metal halides have attracted increasing attention because of their diverse structures and fascinating properties,such as porosity,fluorescence,semi-conductivity,nonlinear optical,thermochromism,photochromism,and effective visible optical catalytic properties.Ionic liquids consisting of pure ionic compositions,not only can afford ionic reaction medium,but also can provide designable template to aid the formation of new structures.~1 In this work,a series of Ag-I compounds were synthesized via the solvothermal reaction of AgI and ionic liquids.Systematic research reveals that ionic liquids are critical for the synthesis.Particularly,the structures are sensitive to the variation of the substitution group from C1 to C4.~2 While,the structures are unsensitive to the variation of the substitution group from C4 to C6.更多还原