【作者】 徐娜； 张巨文； 王秀丽；

【Author】 Na Xu;JuW en Zhang;Xiuli Wang;Department of Chemistry, Bohai University;

【机构】 渤海大学化学化工学院；

【摘要】 近年来,多金属氧酸盐（简称多酸）作为一类独特的无机金属氧簇,因其具有可控制的外形和尺寸、丰富的表而氧原子、较高的负电荷以及优良的性质,如催化、电化学和光化学性能等,已经被广泛用作无机配体或模板剂来制备无机有机杂化物[1,2]。本文以柔性的1,2-双（1H-咪唑-4-甲酰胺）环己烷（L）为有机配体,与钼酸盐和钴离子在水热条件下进行配位组装,合成了一个新的多酸基配合物[CoL(Mo₈O₂₆)_0.5·H₂O]·H₂O（1）。在化合物1中,每个[Co₂L₂]⁴⁺亚单元与Mo₈O₂₆^4-阴离子通过Co-O配位键连接形成1D链,而1D链通过氢键进一步连接形成一个2D超分子网络结构。据我们所知,双咪唑双酰胺配体与多酸的结合目前还没有被报道。更多还原

【Abstract】 Recently,polyoxometalates（POMs）,as a unique class of inorganic metal oxide clusters,have been regarded as excellent candidates of inorganic ligands or templates to obtain inorganic-organic hybrid compounds due to their controllable shapes,sizes,abundant surface oxygen atoms,high negative charges and various properties such as catalytic activity,electrochemistry,and photochemistry.^[1,2].A flexible l,2-bis（1H-imidazole-4-carboxamido） hexamethylene（L） was used as the orangic ligand to assemlbe with molybdate and Co²⁺ ions under hydrothermal condition,resulting in a new POM-based complex[CoL(Mo₈O₂₆)_0.5·H₂O]·H₂O（1）.In compound 1,the[Co₂L₂]⁴⁺ subunits linked Mo₈O₂₆^4- anions through Co-O bond to form 1D chains,which are futher extended into a 2D supramolecular network through hydrogen bonding interaction.To the best of our knowledge,the combination of bis-imidazole-bis-amide ligand with POMs has not been reported up to now.更多还原