【作者】 杨龙奎； 陈忠凯； 杜建龙； 李立军；

【Author】 Long-Kui Yang;Zhong-Kai Chen;Jian-Long Du;Li-Jun Li;Chemical Biology Key Laboratory of Hebei Province,Hebei University;

【机构】 河北大学,河北省化学生物学重点实验室；

【摘要】 Salen型的金属配合物因其易于制备及结构多样性而在过渡金属配位化学中占有重要的地位,是重要的立体化学模型[1,2]。本文基于N,N’-二(3-叔丁基-5-(4’-吡啶基)水杨叉基)-1,2-邻苯二胺(L)和Ni(CH3COO)2·4H2O合成了一种新型的Salen-镍(Ⅱ)配合物。扩散法培养得到配合物的单晶,通过X-ray单晶衍射分析表明,该晶体属于三斜晶系,P-1空间群,晶胞参数:a=10.475(3),b=12.720(4),c=13.627(4),α=97.235(7)o,β=105.437(6)o,γ=113.799(6)o,分子式C38H36N4NiO2,Mr=639.42,V=1544.4(8)3,Z=2,Dc=1.375 Mg/m3,R1=0.0541,wR2=0.0827。更多还原

【Abstract】 Metallosalen complexes,owing to their characteristic properties such as preparative accessibility,structural variety,are important in the field of transition metal coordination chemistry and stereochemistry[1,2].A new mononuclear complex was successfully synthesized on the basis of a Schiff-base ligand L=1,2-phenylendiamine-N,N′-bis(3-tert-butyl-5-(4-pyridyl)salicylidene) and Ni(CH3COO)2·4H2O.Its structure was characterized by single-crystal X-ray diffraction.It crystallized in triclinic system,P-1 space group,with a=10.475(3) ,b=12.720(4) ,c=13.627(4) ,α=97.235(7)o,β=105.437(6)o,γ=113.799(6)o,Molecular formula:C38H36N4NiO2,Mr=639.42,V=1544.4(8) 3,Z=2,Dc=1.375 Mg/m3,R1=0.0541,wR2=0.0827.更多还原