【作者】 林燕； 李晓； 张卫英；

【Author】 LIN Yan,LI Xiao~*,ZHANG Weiying (College of Chemistry and Chemical Engineering,Fuzhou University,Fuzhou,China,350108)

【机构】 福州大学化学化工学院；

【摘要】 <正>双连续相微乳液聚合制备多孔材料,是基于体系中不可聚合的水相在聚合物材料中占据一定体积,将水相除去后即可在聚合物中留下不同结构的孔洞。本文将微乳液聚合技术和分子印迹技术相结合,充分利用微乳液中具有助乳化作用的活性单体作为印迹体系的功能单体,促使模板分子和功能单体在微乳液油水界面进行自组装,然后引发微乳液基体与界面印迹层同步聚合,制备了多孔性的分子印迹聚合物(MIPs)。更多还原

【Abstract】 The porous molecularly imprinted polymers(MIPs) were prepared by simultaneous microemulsion polymerization.L-tryptophan was used as the template molecule and the bicontinuous microemulsion as the precursor systems.The adsorption properties of the MIPs were investigated.When the ratio of BA to MMA was 2:5,the aqueous fraction was 40%,the ratio AA to MMA-BA was 7:3 and the AM percentage in aqueous solution was 5%,the MIPs showed better adsorption.更多还原