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衬底温度对PECVD法生长SiO2薄膜性能影响的研究
Effects of Substrate Temperature on SiO2 Films Deposited by PECVD
【Author】 Gao Shang,Lian Jie,Song Ping,Li Ping,Ma Zheng,Wang Xiao,Wu Shiliang (Shandong University Shandong Jinan 250100)
【机构】 山东大学信息科学与工程学院光电工程系;
【摘要】 使用等离子增强型化学沉积法(PECVD)制备SiO2薄膜具有诸多优点。如何减少产物中的杂质元素以获得更高质量的SiO2薄膜是一个很值得研究的问题。此次实验使用PECVD法在砷化镓衬底上制备二氧化硅薄膜。通过X射线光电子能谱(XPS)分析了衬底温度变化情况下各元素含量的变化,发现杂质元素碳的浓度随着衬底温度的升高大大降低。通过对氮元素的深入分析,发现产物中氮元素主要以Si-N键和N-H键两种方式存在。随着衬底温度的升高,产物中氮化硅的含量也随之降低。通过椭偏测量发现随着衬底温度的提高,二氧化硅薄膜的折射率呈上升趋势。由上述两点可知,随着衬底温度的上升,制备的二氧化硅薄膜的质量明显提高。
【Abstract】 Fabricatingsilica films byplasma enhancedchemical deposition(PECVD) is promising.However in the growth of silica films using PECVD,impurity elements are inevitable.Therefore how to reduce impurity elements is a problem which needs an urgent solution.In this work,we present the results of silica films which are fabricated by PECVD on GaAs substrates of different substrate temperatures.The films are analyzed by X-ray Photoelectron Spectroscopy (XPS).XPS results demonstrates that the ratio of silicon and oxygen of the reaction product is nearly 1:2 and the content of impurity elements in the product of this reaction with a higher substrate temperature is much lower than it is with a lower substrate temperature.And the refractive index of films rises with the increase of substrate temperature.These facts indicate that to gain better SiO 2 films,the substrate temperature should be high.
【Key words】 PECVD; silicondioxide; Ellipsometry; X-rayPhotoelectronSpectroscopy;
- 【会议录名称】 中国光学学会2010年光学大会论文集
- 【会议名称】中国光学学会2010年光学大会
- 【会议时间】2010-08-23
- 【会议地点】中国天津
- 【分类号】O484.1
- 【主办单位】中国光学学会