【作者】 魏艳艳； 赖欣； 毕剑； 高道江； 赁敦敏； 罗怡； 李阳；

【Author】 WEI Yan-yan,LAI Xin,BI Jian,GAO Dao-jiang,LIN Dun-min,LUO Yi,LI Yang (College of Chemistry and Materials Science,Sichuan Normal University,Chengdu 610066,China)

【机构】 四川师范大学化学与材料科学学院；

【摘要】 Sr（MoO₄）_x（WO₄）_1-x固溶体微晶（x=0-0.5）是利用高温固相法合成的。XRD图谱表明这种新型的固溶体微晶为白钨矿型四方晶相结构;微晶的电镜扫描图显示其形貌为四方锥状,纯SrWO₄微晶晶粒大小约为15μm,Mo取代部分W之后,即合成Sr（MoO₄）_0.5（WO₄）_0.5固溶体微晶,晶粒大小减至10μm左右,发射峰的位置移至493nm,强度也有所增加,具有较好的经济价值。更多还原

【Abstract】 Sr（MoO₄）_x（WO₄）_1-x microcrystallines（x=0-0.5） were synthesized by solid-state method.The XRD of microcrystallines showed that the crystal structure were scheelite structure with tetragonal symmetry.The surface morphology was tetragonal taper grains and the grain size of the pure SrWO₄ was about 15μm.When Mo substituted for part of the W to synthesize the Sr（MoO₄）_0.5（WO₄）_0.5microcrystalline,its grain size reduced to 10μm and its emission peek located at 493nm and its strength was also increased than the pure SrWO₄,which possesses high economic value.更多还原