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汞和镉在土壤中的吸附和运移研究进展

A Review of the Study on Adsorption and Migration of Cadmium and Mercury in Soils

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【作者】 王亚平潘小菲岑况刘素芳韩志文

【Author】 WANG Ya-ping~1,PAN Xiao-fei~2,CEN Kuang~3,LIU Su-fang~4,HAN Zhi-wen~5 (1.National Research Center of Geoanalysis,Beijing 100037,China;2.Institute of Geology and Geophysics Chinese Academy of Sciences,Beijing 100029,China;3.China University of Geosciences,Beijing 100083,China;4.Water Resource Bureau of Haidia,Beijing 100089,China; 5.Water Resource Bureau of Daxing,Beijing 102600,China)

【机构】 国家地质实验测试中心中国科学院地质与地球物理研究所中国地质大学(北京)北京市海淀区水资源局北京市大兴区水资源局

【摘要】 介绍了国内外近年来对重要的污染元素汞和镉在土壤中吸附和运移方面的研究成果。评价土壤吸附重金属离子多运用Langmuir、Freundlich及Temkin三种等温吸附曲线。影响土壤吸附汞和镉的因素主要有pH值、有机质、氯离子、土壤组分、土壤类型、竞争吸附离子的参与等。汞的活动性较差,其迁移性质缺乏研究;土壤中镉的二价离子在粘土衬层内的迁移过程中,可生成难溶性沉淀物质,阻碍了液体的渗透,因而导致渗透系数比纯水还低。引用参考文献45篇。

【Abstract】 This paper introduces the recent research progress on adsorption and migration of important pollutants of cadmium and mercury.Isothermal-adsorption curves based on Langmuir equation,Freundlich equation and Temkin equation are used to estimate adsorbing capacity of the soils for heavy metal ions.It is found that main factors that affect cadmium and mercury adsorbing by soils are pH,organic materials,chloride ions,soil composition and types,other adsorption-competing ions.Few research results on mercury migration are obtained because of its inactive characteristic.It is also found that the penetrating coefficient of bivalent cadmium in clay laver is less than that of pure water because during the migration bivalent cadmium forms precipitants and blocks liquid migration.45 references are cited.

【基金】 中央级科研院所社会公益研究项目(2001DIA10021);国家重点基础研究发展规划项目(TG1999045700)
  • 【会议录名称】 中国科学院地质与地球物理研究所二○○三学术论文汇编·第五卷(矿产资源与水资源)
  • 【会议名称】中国科学院地质与地球物理研究所2003学术年会
  • 【会议时间】2003-12-01
  • 【会议地点】中国北京
  • 【分类号】X53
  • 【主办单位】中国科学院地质与地球物理研究所(Institute of Geology and Geophysics Chinese Academy of Sciences)
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