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聚苯乙烯/聚苯胺核壳粒子的制备与电化学性能研究

The preparation and the research of electrochemical properties of polystyrene/polyaniline core-shell particles

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【作者】 黄彬江奇赵晓锋何正文赵勇

【Author】 HUANG Bin1, Jiang Qi1, ZHAO Xiao-feng1, HE Zheng-wen1, ZHAO Yong1,2 (1.Key Laboratory of Advanced Technologies of Materials (Ministry of Education of China) and Superconductivity R&D Center, Southwest Jiaotong University, Chengdu 610031,China; 2. School of Materials Science and Engineering, University of New South Wales, Sydney, 2052 NSW, Australia)

【机构】 西南交通大学超导研究开发中心材料先进技术教育部重点实验室School of Materials Science and Engineering,University of New South Wales

【摘要】 采用化学氧化法制备聚苯乙烯胶体粒子,并以此为模板成功地制备了聚苯乙烯/聚苯胺核壳型纳米复合材料。运用扫描电子显微镜(SEM)对其进行表征,并通过循环伏安研究样品的电化学特性,结果表明,聚苯乙烯/聚苯胺复合材料具有特殊的核-壳,对复合材料的导电性能起到明显的促进作用,其复合材料的单电极比容量达到147F/g。

【Abstract】 Polystyrene colloid particals were achieved via chemical oxidation method and were used as model for preparing Polystyrene /polyaniline core-shell nanocomposite. The structure and morphology were characterized by the scanning electron microscope (SEM) test and the electrochemical property was characterized by the test of cyclic voltammetry (CV). It was indicated that the composites with special core-shell structure were greatly effective to enhance the conductivity of the material. Furthermore, the specific capacitor of single electrode with composites was 147 F/g.

【关键词】 聚苯乙烯/聚苯胺核-壳粒子比容量
【Key words】 polyaniline/polystyrenecore-shellcapacity
【基金】 国家杰出青年科学基金资助项目(50588201);四川省科技攻关计划资助项目(05GG009-0032006Z02-006-1);四川省应用基础研究基金资助项目(2008JY0061);西南交通大学基础科学研究基金资助项目(2007B20)
  • 【会议录名称】 2009中国功能材料科技与产业高层论坛论文集
  • 【会议名称】2009中国功能材料科技与产业高层论坛
  • 【会议时间】2009-11-07
  • 【会议地点】中国江苏镇江
  • 【分类号】O631.3
  • 【主办单位】中国仪表功能材料学会、江苏大学、《功能材料》期刊、《功能材料信息》期刊
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