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造孔剂对SOFC性能的影响

The effect of pore formers on the performance of SOFC

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【作者】 沈哲敏孙克宁王振华乔金硕张乃庆

【Author】 SHEN Zhe-min1, SUN Ke-ning2, WANG Zhen-hua1, QIAO Jin-shuo2, ZHANG Nai-qing2 (1.School of Chemical Engineering and Technology, Harbin Institute of Technology, Harbin 150001,China; 2.Academy of Fundamental and Interdisciplinary Sciences, Harbin Institute of Technology, Harbin 150001, China)

【机构】 哈尔滨工业大学化工学院哈尔滨工业大学基础与交叉科学研究院

【摘要】 采用流延成型技术制备阳极支撑型固体氧化物燃料电池(SOFC),研究了造孔剂对流延成型SOFC性能的影响。采用PMMA和淀粉作为造孔剂,研究了其含量分别为5%,10%和15%时的电池性能。通过实验发现,在造孔剂含量较低时,使用PMMA的电池性能较好;而采用10%淀粉作为造孔剂的电池性能最好,在800℃下电池最大功率密度为558mW/cm2。SEM照片显示,淀粉含量为10%的电池阳极具有较理想的微观结构。

【Abstract】 The effect of pore formers on the performance of an anode supported-SOFC, fabricated by tape-casting technology, was investigated in the paper. PMMA and starch were used to make pore in anodes, and the contents of pore former were 5%, 10% and 15% respectively. The results indicated that the cell with PMMA as pore former was of better performance when the pore former content in anodes is lower. With 10% starch in anode, the cell had a best performance at 800℃, which is of the maximum power density of 558 mW/cm2. SEM observation showed that the anode with 10% starch was of the good microstructure.

【关键词】 固体氧化物燃料电池阳极造孔剂淀粉PMMA
【Key words】 solid oxide fuel cellanodepore formerstarchPMMA
【基金】 国际科技合作计划资助项目(2006DFA52660)
  • 【会议录名称】 2009中国功能材料科技与产业高层论坛论文集
  • 【会议名称】2009中国功能材料科技与产业高层论坛
  • 【会议时间】2009-11-07
  • 【会议地点】中国江苏镇江
  • 【分类号】TM911.4
  • 【主办单位】中国仪表功能材料学会、江苏大学、《功能材料》期刊、《功能材料信息》期刊
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