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掺铒氟化物玻璃ZBLALip光谱性质和Judd-Ofelt理论分析
Spectroscopic properties and Judd-Ofelt theory analysis of Er3+doped ZBLALip based glasses
【作者】 石梦静; 蔡添志; 张磊; 马乐; 刘月; 蔡志平; 许惠英;
【Author】 SHI Meng-jing~1 CAI Tian-zhi~1 ZHANG Lei~1 MA Le~1 LIU Yue~2 CAI Zhi-ping~2 XU Hui-ying~2 (1.Department of Physics,Xiamen University,Xiamen 361005,China; 2.Department of Electronic Engineering,Xiamen University,Xiamen 361005,China)
【摘要】 测量了常温下,Er3+离子在氟化物玻璃 ZBLALip 中的吸收光谱和荧光寿命;应用 Judd-Ofelt 理论计算了 Er3+离子的谱线强度、自发辐射几率 A、荧光分支比β和辐射寿命τrad等光谱参量,并拟合了相应的强度参数Ω(t=-2,4,6),分别为Ω2=2.80×10-20cm2,Ω4=0.95×10-20cm2,Ω6=0.94×10-20cm2; 利用 McCumber 理论计算了能级4Ⅰ13/2→4Ⅰ15/2跃迁的受激发射截面σem;通过计算发现,该材料的量子效率较高,达到90%,可成为新的激光材料,为拉制高 Q 值的光学介质微球腔提供了参考。
【Abstract】 A new fluoride glass composition revealing a high stability,with a weak nucleation tendency,has been studied.The Judd-Ofelt intensity parameter Ωt(t=2,4,6)of a novel Er3+doped ZBLALip based glasses deriving from the absorption spectra were acquired as followS:Ω2=2.80×10-20cm2, Ω4=0.95×10-20cm2,Ω6=0.94×10-20cm2.McCumber theory was used to calculate the stimulated emission cross section of 4I13/2→4I15/2transition,the result was 4.2×10-21cm2.In addition,the lifetime of the 4I13/2 level of Er3+ions was 9.2 ms,and the quantum efficiency was 90%.The novel Er3+doped glasses can be used in fabricationing high Q quality factor dielectric microcavities.
【Key words】 Spectroscopic properties; Er3+ doped; Judd-Ofelt theory;
- 【会议录名称】 2007年先进激光技术发展与应用研讨会论文集
- 【会议名称】2007年先进激光技术发展与应用研讨会
- 【会议时间】2007-07
- 【会议地点】中国吉林长春
- 【分类号】O482.3
- 【主办单位】中国宇航学会光电技术专业委员会