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腐蚀对水泥土强度的影响机理及试验研究

Chemical Mechanism and Experimental Study on Strength of Cemented Soil under Corrosive Environment

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【作者】 韩鹏举白晓红贺武斌王梅

【Author】 HAN Peng-ju BAI Xiao-hong HE Wu-bin WANG Mei (College of Architecture and Civil Engineering,Taiyuan Univ of Technology,Taiyuan,Shanxi 030024)

【机构】 太原理工大学建筑与土木工程学院

【摘要】 通过模拟试验的方法探讨了在不同硫酸溶液和硫酸镁溶液环境下不同龄期的水泥土表观和抗压强度变化规律和pH值、Mg2+浓度和SO42-浓度随时间的变化关系,得出了两种腐蚀环境下水泥土表面腐蚀程度均随着腐蚀时间的增长和溶液浓度的增大而增加,水泥土抗压强度均随溶液浓度的增大而减小;揭示了腐蚀环境介质对水泥土腐蚀的化学作用机理,最后得出硫酸溶液环境下水泥土强度的改变与溶液中的PH值和SO42-浓度密切相关,硫酸镁溶液环境下水泥土强度的改变与Mg2+浓度和SO42-浓度密切相关,并且得出SO42-相同条件下,阳离子为H+的硫酸比阳离子为Mg2+的硫酸镁对水泥土侵蚀严重.

【Abstract】 In turn to cause some serious damage to the structure.In order to simulate and study the erosion effect process such as the changes of corrosive degree of surface,unconfined compression strength of cemented soil sample and the Ph values,Mg2+ concentration and SO42- concentration of corrosive solutions,a series of tests are conducted on the cemented soil blocks which were cured in different concentrations of H2SO4 and MgSO4 so- lutions including taking photos,unconfined compressive strength tests,measuring Ph value,Mg2+ concentration and SO4<sup>2- concentration.The results of tests show that the corrosive degree of samples’ surfaces is increasing and the unconfined compression strength is decreasing with the increase of corrosive solution concentration at the same erosion time,and the corrosive degree is increasing with the corrosive time in both H2SO4 solution and MgSO4 solution.At the same time,after analyzing chemical effect mechanism of contents of corrosive environ- ment on cemented soil and studying the relationships between the pH values and concentration of SO42- of H2SO4 solution,the concentration of Mg2+ and SO42- of MgSO4 solution,and corrosive time,it is concluded that com- pressive strength is closely rated with the Ph values and SO42- concentration of H2SO4 corrosive environment, and with the Mg2+ concentration and SO42- concentration of MgSO4 corrosive environment respectively,and H+ corrosive effect effecting is obviously stronger than Mg2+ in the same SO42- concentration.

【基金】 山西省留学人员回国基金资助项目(2006-26);高等学校博士点专项基金资助项目(20070112003)
  • 【会议录名称】 第二届全国环境岩土与土工合成材料技术研讨会论文集(一)
  • 【会议名称】第二届全国环境岩土与土工合成材料技术研讨会
  • 【会议时间】2008-11
  • 【会议地点】中国湖南长沙
  • 【分类号】TU472
  • 【主办单位】中国岩石力学与工程学会环境岩土工程分会、中国土木工程学会土力学及岩土工程分会、中国土工合成材料工程协会
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