【作者】 梅光泉； 袁晓玲； 曾锦萍；

【Author】 Mei Guang-Quan~* Yuan Xiao-Ling Zeng Jin-ping Key Laboratory of Jiangxi University for Applied Chemistry and Chemical Biology,Yichun University, Yichun 336000 China

【机构】 宜春学院江西省高校应用化学与化学生物学重点实验室；

【摘要】 <正>金属四氮杂卟啉,在半导体、激光记录材料、LB 膜、高能电池等高技术领域显示了优异性能而受到特别关注,而钯配合物具有丰富的光学和催化性能以及分子识别和交换等生物功能,在化学气更多还原

【Abstract】 In this paper, ligand of meso-tetra（4-carboxyphenyl）porphyrin has been synthesized, and palladium（Ⅱ） complexe was obtained by the reaction of the ligand and palladium chloride. Molecular structures of the synthesized compounds were confirmed by elemental analysis,conductivity measurement, UV-Vis spectra,IR spectra,¹H NMR spectra and ESI-MS.The configuration and bonding character of complexe were discussed.Thermogravimetry（TG） and differential scanning calorimetry（DSC） for two compounds in an atmosphere of N₂ were performed.In the chelating ring,conjugate π bonds were formed, which further strengthen the Pd-N coordination bonds and made Pd（Ⅱ） complex a stable compound.更多还原