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水泥窑布袋捕集灰中PCDD/Fs,PCBs和PCNs的分布特征
Patterns of PCDD/Fs, PCBs and PCNs Homologues in Fly Ash Formed from Cement Kilns
【作者】 张婧; 倪余文; 张海军; 张雪萍; 张青; 陈吉平;
【Author】 Zhang Jing, Ni Yuwen, Zhang Xueping, Zhang Haijun, Zhang Qing, Chen Ji-ping (Dalian Institute of Chemical Physics, CAS, Dalian 116023, China)
【机构】 中国科学院大连化学物理研究所;
【摘要】 <正>近年来,国外对于燃烧废弃物水泥窑的POPs排放研究日益增多[1,2],主要集中在烟气烟尘中POPs排放总量、排放因子和PCDD/Fs分布方面[1-3]。本项研究采集了湿法旋窑(1台)、新型干法旋窑(1台)和机械立窑(3台)的除尘器捕集灰。
【Abstract】 The concentrations and the patterns, toxic equivalent (TEQ) values of dioxin-like chemicals in fly ash collected from three types of cement kilns (vertical shaft kiln, wet-process rotary kiln and dry-process rotary kiln) were determined by isotope dilution and HRGC-HRMS, and the results were compared with that of fly ash from two types of waste incinerators. The results showed that the total concentration of PCDD/Fs, PCBs and PCNs in cement kiln fly ash, which were in the range of 0.449~7.347 ng·g-1,0.709~25.15 ng·g-1and 0.563~10.42 ng·g-1 respectively, were further lower than that of fly ash from waste incinerators.
【Key words】 PCDD/Fs; PCBs; PCNs; cement kilns; waste incinerators; fly ash; patterns;
- 【会议录名称】 中国化学会第26届学术年会环境化学分会场论文集
- 【会议名称】中国化学会第26届学术年会环境化学分会场
- 【会议时间】2008-07
- 【会议地点】中国天津
- 【分类号】X701.2
- 【主办单位】中国化学会