【作者】 于贤勇； 蔡淑惠； 陈忠；

【Author】 YU Xian-yong CAI Shu-hui CHEN Zhong~* (Departments of Physics and Chemistry,State Key Laboratory for Physical Chemistry of Solid Surface,Xiamen University,Xiamen 361005)

【机构】 厦门大学物理系和化学系,固体表面物理化学国家重点实验室；

【摘要】 <正>过氧钒配合物除了作为氧转移试剂外,在生物体内可抑制或激活多种与磷酸转移过程有关的酶,起类胰岛素的作用,对它的研究已成为化学和生物学科的热点之一。目前主要采用核磁共振、拉曼光谱和从头计算等方法研究过氧钒配合物的化学性质及其与其它分子的相互作用,以探索其活性机制的本质和基础。更多还原

【Abstract】 Peroxovanadate complexes not only have been employed as catalysts or as oxo transfer reagents for alcohol,arenas,alkenes and thioethers,but also give rise to an insulin mimetic response and other biological responses.Therefore,the chemistry of peroxovanadate compounds under physiological condition and their interactions with small molecules are among the most challenging fields which can be studied by NMR, Raman,and ab initio calculations,etc.更多还原