【作者】 吴亚盘； 吴威平； 王萃娟； 周彩华； 王尧宇； 史启祯；

【Author】 Ya-PanWu Wei-Ping Wu Cui-Juan Wang Cai-Hua Zhou Yao-Yu Wang Qi-Zhen Shi (Department of Chemistry/Shaanxi Key Laboratory of Physico-inorganic Chemistry, Northwest University, Xi’an 710069)

【机构】 西北大学化学系／陕西省物理无机化学重点实验室；

【摘要】 本文以三嗪衍生物为封端配体、羟基二元羧酸为桥联配体,借助超分子作用力构筑了含有一维开放隧道的三维超分子配位聚合物{[Cu(dpdapt)(H2dhbd)]·6H2O}(1)。有趣的是,在一维隧道中占据有(H2O)6 六元环水簇1D链,羟基二元羧酸中未配位的羟基氧对水簇链起到了稳定作用。更多还原

【Abstract】 In this paper, a 3-D supramolecular coordination polymer containing 1-D open channels was synthesized by using of 1,3,5-triazine derivative as terminal ligand and 2,3-dihydroxybutanedioic dianion as bridges. Interestingly, the hexameric water clusters stabilized by the uncoordinated hydroxyl oxygen atoms of carboxylate self-assemble a novel 1-D water cluster chain via water-water interaction along the 1-D channels.更多还原