节点文献
簇聚合物[Bu4N]n[Ag2I3]n的合成、结构及三阶非线性性能
Synthesis, crystal structure and third-order non-linear optical properties of cluster polymer [Bu4N]n[Ag2I3]n
【Author】 Zhao-Xia Zhang, Yong Li*, Wen-Dong Song College of Science, Guangdong Ocean University, 524088, Zhanjiang
【机构】 广东海洋大学理学院;
【Abstract】 The low temperature solid-state reaction of AgCl, and Bu4NI forms the complex of novel structure [Bu4N][Ag2I3]. The crystal of the cluster polymer belongs to orthorhombic, space group Pnma, with the crystal cell parameters: a = 7.3670(13) ?, b = 12.579(4) ?, c = 18.158(4) ?, V = 1682.7(7) ?3, Z = 8, R1 = 0.0587, wR2 = 0.1285. The third-order nonlinear absorption coefficient and third-order nonlinear refractive index are respectively, α2 = 6.37×10-11 m/w and n2 = –3.6×10-18 m2/w.
【基金】 广东海洋大学博士启动基金(0512101);湛江引进人才创业项目(0509044)资助。
- 【会议录名称】 中国化学会第二十五届学术年会论文摘要集(下册)
- 【会议名称】中国化学会第二十五届学术年会
- 【会议时间】2006-07
- 【会议地点】中国吉林长春
- 【分类号】O635
- 【主办单位】中国化学会