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有机-无机杂化磷酸锆的超分子插层组装

Supramolecular Intercalation and Assembly of Layered Zirconium Phosphonate-phosphate

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【作者】 曾仁权傅相锴孙美丹

【Author】 Ren-Quan Zeng1,2, Xiang-Kai Fu1,*, Mei-Dan Sun1 1. College of Chemistry and Chemical Engineering, Southwest University, 400715, Chongqing; 2. College of Rongchang, Southwest University, 402460, Chongqing

【机构】 西南大学化学化工学院

【Abstract】 Supramolecular chemistry have been much more paid attentions, because they are extensively applied in many fields such as ion-exchange, adsorbent, catalysis, druggery, electrochemistry, biology, photochemistry, environment. Supramolecular compounds are prepared by intercalation and assembly of basic amino acids (i.e. L-arginine, L-lysine or L-histidine) into layered zirconium (proline-N-methylphosphonate-phosphate), and characterized by element analysis, ICP, XRD, FTIR, Raman spectra and TG-DSC. The results indicate that FT-IR, Raman spectra and thermal stability of the supramolecular compounds are different from that of α-ZPMPP host, and basic amino acid molecules are formed monolayers in the interlayer galleries of α-ZPMPP host.

  • 【会议录名称】 中国化学会第二十五届学术年会论文摘要集(上册)
  • 【会议名称】中国化学会第二十五届学术年会
  • 【会议时间】2006-07
  • 【会议地点】中国吉林长春
  • 【分类号】O621.25
  • 【主办单位】中国化学会
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