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无溶剂条件下钯催化交叉偶联反应研究

Palladium-Catalyzed Cross-Coupling Reactions under Solvent-Free Conditions

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【作者】 谢叶香邓辰亮唐伯孝梁云尹笃林李金恒

【Author】 Ye-Xiang Xie, Chen-Liang Deng, Bo-Xiao Tang, Yun Liang, Du-Lin Yin, Jin-Heng Li* Key Laboratory of Chemical Biology & Traditional Chinese Medicine Research (Ministry of Education), College of Chemistry and Chemical Engineering, Hunan Normal University, Changsha 410081

【机构】 湖南师范大学化学化工学院化学生物学与中药分析教育部重点实验室

【Abstract】 Palladium-catalyzed cross-coupling reactions have become important and usable transformations for the synthesis of natural products, important pharmaceuticals and building blocks in organic synthesis. We found that the palladium/phosphine ligand catalytic system-catalyzed Sonogashira cross-cpoupling reaction, Hiyama cross-coupling reaction and Suzuki cross-cpoupling reaction were conducted smoothly and efficeiently using TBAF as the base under solvent-free conditions .

【关键词】 无溶剂交叉偶联反应
  • 【会议录名称】 中国化学会第二十五届学术年会论文摘要集(上册)
  • 【会议名称】中国化学会第二十五届学术年会
  • 【会议时间】2006-07
  • 【会议地点】中国吉林长春
  • 【分类号】O643.32
  • 【主办单位】中国化学会
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