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取代四苯基钴卟啉催化剂的合成及构效关系研究

Study on Synthesis and QSAR of Substituted Cobalt Porphyrins

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【作者】 张天慧； 佘远斌； 王兰芝；

【Author】 Tian-Hui Zhang, Yuan-Bin She, Lan-Zhi Wang Institute of Green Chemistry and Fine Chemicals, Beijing University of Technology, 100022 Beijing

【机构】 北京工业大学绿色化学与精细化工研究所；

【Abstract】 The catalytic activities of cobalt porphyrin catalysts vary with their structures. Consequently exploring the QSAR of cobalt porphyrin catalysts was one of the extremely attractive investigations. In this paper, substituted cobalt-porphyrin catalysts were synthesized and characterized. Catalytic activities of these catalysts were investigated by means of dioxygen liquid-phase oxidation of p-nitrotoluene (PNT) to p-nitrobenaldehyde as the model reaction. The QSAR of cobalt porphyrin catalysts was emphatically investigated and the regression equation TON=39639.79-440.24ELUMO-3054.11EL-H was obtained.

【关键词】 钴卟啉； 合成； 构效关系；
【基金】 国家自然科学基金面上项目(20576005);北京市自然科学基金重点项目(2061001)
  • 【会议录名称】 中国化学会第二十五届学术年会论文摘要集（上册）
  • 【会议名称】中国化学会第二十五届学术年会
  • 【会议时间】2006-07
  • 【会议地点】中国吉林长春
  • 【分类号】O643.32
  • 【主办单位】中国化学会
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