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EQCM和原位FTIR反射光谱研究碱性介质中异丙醇在铂电极上电氧化过程(英文)
Studies on the electrooxidation of isopropanol in alkaline media using EQCM and in-situ FTIRs
【作者】 林珩; 陈国良; 林进妹; 周剑章; 文莉; 林仲华;
【Author】 LIN, Heng CHEN, Guo-Liang LIN, Jin-Mei ZHOU, Jian-Zhang WIN, Li LIN, Zhong -Hua (Department of Chemistry, Zhangzhou Nornal College, Zhangzhou 363000,State Key Laboratory of Physical Chemistry of the Solid Surfaces, College of Chemistry and Chemical Engineering, Institute of Physical Chemistry, Xiamen University, Xiamen 361005)
【机构】 漳州师范学院化学系; 厦门大学化学化工学院化学系固体表面物理化学国家重点实验室;
【摘要】 <正>The electrochemical oxidation of small organic molecules is of fundamental importance in electrocatalysis, and is also a key factor in the application of the oxidation as anodic process in direct fuel cells. Due to the particularity of the molecular structure, isopropanol is the only molecule among C3 alcohol that fails to dissociate into CO at the surface of platinum electrodes in acidic media. Although a direct fuel cell based on an alkaline electrolyte is more promising, little attention has been paid to in situ IR spectroscopic and EQCM investigations of the oxidation of small organic molecules in alkaline media because of the progressive
- 【会议录名称】 第十三次全国电化学会议论文摘要集(上集)
- 【会议名称】第十三次全国电化学会议
- 【会议时间】2005-11
- 【会议地点】中国广东广州
- 【分类号】O646.54
- 【主办单位】中国化学会电化学委员会