【作者】 吴悦； 杨帆； 杨新国； 张建华； 汪茫； 李海洋； 何丕模； 鲍世宁；

【Author】 Wu Yue1 Yang Fan1, Yang Xinguo2, Zhang Jianhua1, Wang Mang2, Li Haiyangi1, He Pimo1 and Bao Shining1 1 Physics Department Zhejiang University, Hangzhou, 310027, P.R.China 2 Department of Polymer Science and Energy Zhejiang University, Hangzhou, 310027, P.R.China

【机构】 浙江大学物理系； 浙江大学高分子材料系；

【摘要】 本工作利用UPS与ARUPS对有机半导体材料5-(N-正丁基-3,4,9,10-苝四甲酸亚酰胺-N’-苯基)-10,15,20-三苯基卟啉在Ru(0001)上的界面特性进行了研究。研究结果表明,在Ru(0001)表面上,与有机半导体材料价带电子轨道有关的谱峰分别位于费米能级以下4.5、6.8和9.2ev处,其最高占据态(价带顶位置)位于费米能级以下1.5eV处。在衬底温度低于200oC时,该有机半导体材料能够在Ru(0001)上稳定吸附,在Ru(0001)上的脱附开始于在200oC。ARUPS结果显示,构成该材料分子的卟啉和苝两个稠环不在同一个平面内,即该材料分子中的两个稠环平面成一定的夹角,至少有一个稠环平面与衬底表面不平行。更多还原

【Abstract】 The electronic structure、thermal stability and molecule orientation of 5- (N- n- butyl- 3, 4, 9, 10- perylene tetracarboxyl icimide-N‘-phenyl)-10, 15, 20- triphenylporphyrin growth on Ru(0001) surface has been studied with ultraviolet photoemission spectroscopy, three emission features of the organic material are observed at 4.5, 6.8 and 9.2 ev respectively and the HOS is located at 1.5ev below the Fermi level. The decomposition of the adsorbed organic substance on Ru(0001) surface is at roughly 200oC. The angle-resolved ultraviolet photoemission spectroscopy results suggest that the two condensed nucleus which compose the organic material, porphyrin and perylene, are not in the same plane. There exists an angle between these two planes of the condensed nucleus, one plane is not paralleled to the substance.更多还原