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氧化铜对高胶凝性熟料矿物形成及固溶的影响

Influence of CuO on mineral formation and solid solution of high cementing clinker

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【作者】 马素花沈晓冬龚学萍钟白茜

【Author】 Ma Suhua Shen Xiaodong Gong Xueping Zhong Baixi (College of Material Science and Engineering, Nanjing University of Technology, Nanjing 210009, China)

【机构】 南京工业大学材料科学与工程学院

【摘要】 借助化学分析法测定了水泥熟料中C4A3S矿物的含量和Cu2+离子在熟料中的浸出率,用X射线内标法测定了水泥熟料中C3S含量;用X射线衍射和差热分析研究了矿物形成过程;并采用扫描电镜和透射电镜分别研究矿物形貌和C3S晶体结构.研究结果表明:生料中掺入一定量的CuO,能降低水泥熟料的烧成温度,促进C3S和C4A3S两种矿物相互共存.过高的CuO亦会降低C4A3S矿物的分解温度.

【Abstract】 Content of calcium sulphoaluminate and soke content of Cu2+ in clinkers were determined by chemical analysis, and content of tricalcium silicates was determined by X-ray diffraction. The mineral composition and clinkering property of clinkers were investigated by X-ray diffraction (XRD) and differential scanning calorimetry (DSC). The shape of calcium sulphoaluminate and structure of tricalcium silicates crystal were investigated respectively by scanning electron microscope and transmission electron microscope. The results show that adding a reasonable amount of CuO in raw meal could lower the clinkering temperature, and promote the coexistence of C3S and C4A3S . However extra amount of CuO may lower the decomposition temperature of C4A3S .

【基金】 国家重点基础研究发展计划(973计划)资助项目(2001CB610701);江苏省“六大人才高峰”资助项目.
  • 【会议录名称】 2005年全国博士生学术论坛(土木建筑学科)论文集
  • 【会议名称】2005年全国博士生学术论坛(土木建筑学科)
  • 【会议时间】2005-08
  • 【会议地点】中国南京
  • 【分类号】TQ172.7
  • 【主办单位】国务院学位委员会办公室、教育部学位管理与研究生教育司
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