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SiO2凝胶玻璃基质中酞菁钴的原位合成及表征
In-situ Synthesis and Charaterization of Copper Phthalocyanine in Sol-gel Silica Matric
【Author】 ZHAN Hong-bing;PENG Yi-ru;CHEN Wen-zhe;WANG Min-quan College of Materials Science and Engineering; The Institute of Functional Materials Fuzhou University, Fuzhou. 350002, China; Department of Materials Science and Engineering, Zhejiang University Hangzhou, 310027, China
【机构】 福州大学材料学院； 功能材料研究所； 浙江大学材料系；
【摘要】 引入纳米化学复合的新概念,以邻苯二甲腈为原料,采用模板法在SiO2 凝胶玻璃基质的形成过程中原位合成了酞菁钴。用IR、UV/Vis、元素分析等方法对其进行了表征,并对其合成机理进行了讨论。
【Abstract】 Phthalocyanine and its metal-ligands have excellent optic-electricity properties. But their low solubility insol-gel precursor makes it difficult to get their homogeneously composites with traditional Sol-gel schedule. Toovercome this problem, an in-situ synthesis technique was successfully used to syntheses CoPc in silica sol-gel matrics.As the result, a new kind of organic/inorganic nanocomposite was got. The characterization was carried out by methodsof IR、UV/Vis and Element Analysis. The synthesis mechanism of CoPc was also discussed.
【Key words】 copper phthalocyanine； sol-gel silica matric； IN-situ synthesis；
- 【会议录名称】 第四届中国功能材料及其应用学术会议论文集
- 【会议名称】第四届中国功能材料及其应用学术会议
- 【会议时间】2001-10
- 【会议地点】中国厦门
- 【分类号】TQ171
- 【主办单位】中国仪器仪表学会仪表材料分会