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Al85Y4Nd4M7(M=Fe、Co)和Al85Zr4Nb4M7(M=Fe、Co)快凝合金的组织和热稳定性

Microstructure and Thermal Stability of Rapidly Solidified Al85Y4Nd4M7(M=Fe,Co) and Al85Zr4Nb4M7(M=Fe,Co) Alloys

【作者】 胡磊

【导师】 陈翌庆;

【作者基本信息】 合肥工业大学 , 材料加工工程, 2004, 硕士

【摘要】 本文利用单辊旋铸技术(冷速105</sup>106k/s)制备了快速凝固Al85Y4Nd4Co7、Al85Nb4Zr4Co7、Al85Y4Nd4Fe7和Al85Y4Nd4Fe7(原子百分数比)合金薄带,利用XRD、DSC、TEM、HREM等分析手段对每一种快凝合金薄带的急冷态,退火态显微组织进行了研究。分析了Co、Fe对快速凝固Al-Y-Nd系和Al-Y-Zr系合金的显微组织和性能的影响。分析研究在高温情况下快速凝固Al85Nb4Zr4Co7、Al85Nb4Zr4Co7、Al85Y4Nd4Fe7和Al85Y4Nd4Fe7合金的相及组织演化的过程。 研究表明:1)快速凝固Al85Nb4Zr4Co7合金急冷态组织为完全的非晶态组织。2)快速凝固Al85Nb4Zr4Co7合金急冷态组织中存在α-Al基体相以及一定体积分数的Al3Nb相和Al9Co2相。3)快速凝固Al85Y4Nd4Fe7合金急冷态组织为完全的非晶态组织。在340℃×1。5h退火条件下,出现α-Al晶体以及少量的未知晶粒。4)快速凝固Al85Y4Nd4Fe7合金在室温条件下已发生相的转变过程,DSC曲线中未出现大的放热峰。在合金急冷态组织中存在α-Al基体和Al13Fe4相以及未知相。5)通过对Al85Nb4Zr4Co7合金和Al85Y4Nd4Fe7合金急冷态和退火态相组成和显微组织的比较,两种合金在急冷态状态下都形成完全非晶态组织;Al85Y4Nd4Fe7合金热稳定性优于Al85Nb4Zr4Co7合金。两者开始结晶温度分别为300℃和220℃。在三种不同温度退火处理过程中,Al85Nb4Zr4Co7合金晶粒生长速率比Al85Y4Nd4Fe7合金晶粒大。金属元素Co和Fe的加入有利于合金非基的形成,其中Fe可以显著提高热稳定性。这为将快速凝固Al基合金应用为高温耐热材料提供了理论依据。

【Abstract】 Rapidly solidified Al85Y4Nd4Fe7, Al85Zr4Nb4Fe7, Al85Zr4Nb4Co7 and Al85Y4Nd4Co7 (at %) alloys were prepared by melt spinning. As-quenched and as-annealed microstructures were studied by DSC, XRD, TEM and HREM. The paper analyzed the influences of Co and Fe elements for the microstructures of the rapidly solidified Al-Y-Nd and Al-Y-ZrAl-Fe alloy ,respectively, and analyzed the revolutions of Al85Y4Nd4Fe7, Al85Zr4Nb4Fe7, Al85Zr4Nb4Co7 and Al85Y4Nd4Co7 alloys at the higher temperatures.The study indicates that: l)fully amorphous structure could be obtained in the rapidly solidified A185Y4Nd4Co7 alloy ribbons. 2) simultaneous precipitation occurs at room temperatures, which are the phases of α-Al Al3Nb and Al9Co2, in the rapidly solidified Al85Zr4Nb4Co7 alloy ribbons. 3) fully amorphous structure could be obtained in the rapidly solidified A185Y4Nd4Fe7 alloy ribbons. 4) simultaneous precipitation occur at room temperatures in the rapidly solidified Al85Y4Nd4Fe7 alloy ribbons. 5) The thermal stability of the Al85Y4Nd4Fe7 amorphous alloy is higher than that of the Al85Y4Nd4Co7 amorphous alloy, which indicates that Fe element can enhance the thermal stability in Al-Y-Nd-M (M=Fe Co).

  • 【分类号】TG113
  • 【被引频次】3
  • 【下载频次】53
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