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Gd对Fe66Cr2Nb4Y6B22合金的非晶形成能力和力学性能的影响

Effect of Gd on Glass Forming Ability and Mechanical Properties of Fe66Cr2Nb4Y6B22 Alloy

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【作者】 张娜; 张伟; 武彧婷; 向青春; 任英磊; 邱克强;

【Author】 ZHANG Na;ZHANG Wei;WU Yu-ting;XIANG Qing-chun;REN Ying-lei;QIU Ke-qiang;School of Materials Science and Engineering, Shenyang University of Technology;

【通讯作者】 邱克强;

【机构】 沈阳工业大学材料科学与工程学院;

【摘要】 Gd作为优异的中子吸收剂,在中子吸收元素中具有最大的热中子俘获截面。采用铜金属型铸造法研究了Fe66Cr2Nb4Y6-xGdxB22(x=2,4,5,6 at.%)合金的非晶形成能力及力学性能。结果表明:当Gd含量为2 at.%和4 at.%时,两种合金的非晶形成能力分别为3 mm和4mm。进一步提高Gd含量,合金的非晶形成能力低于3 mm。Fe66Cr2Nb4Y2Gd4B22合金具有最大的非晶形成能力,其过冷液相区ΔTx、约化玻璃转变温度Trg和非晶形成能力判定参数γ均达到最大值,分别为56 K,0.667 3和0.424 1。但是Fe66Cr2Nb4Y6-xGdxB22(x=2 at.%,4 at.%,5 at.%)非晶合金的抗压强度和显微硬度随Gd含量的增加而降低。

【Abstract】 As an excellent neutron absorber,Gd has the largest thermal neutron capture cross section in the neutron absorbing elements.The amorphous forming ability and mechanical properties of Fe66Cr2Nb4Y6-xGdxB22(x=2 at.%,4 at.%,5 at.%,6 at.%)alloy were studied by copper-mould cast.The results showed that when the Gd content was 2 at.%and 4 at.%,the glass-forming ability of both alloys was 3 mm and 4 mm,respectively.Further increasing the Gd content,the glass-forming ability of the rest alloys was less than 3 mm.The Fe66Cr2Nb4Y2Gd4B22 alloy exhibits the largest glass-forming ability,the corresponding supercooled liquid region,ΔTx,the reduced glass transition temperature,Trg,and the criteria for determining the glass-forming ability,γ,all reached the maximum value of 56 K,0.667 3 and 0.424 1,respectively.

  • 【文献出处】 铸造 ,Foundry , 编辑部邮箱 ,2024年09期
  • 【分类号】TG139.8
  • 【下载频次】15
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