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硅烷偶联剂改性蒙脱土/SBS/HVA高黏改性沥青最佳掺量确定及其性能评价

Determination of optimum dosage of high-viscosity-modified asphalt based on silane-coupling-agent-modified montmorillonite/SBS/HVA blends and its performance

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【作者】 孙吉书濮夏天杨凯靳灿章

【Author】 SUN Jishu;PU Xiatian;YANG Kai;JIN Canzhang;School of Civil Engineering and Transportation,Hebei University of Technology;Tianjin Municipal Engineering Design Institute;

【通讯作者】 濮夏天;

【机构】 河北工业大学土木与交通学院天津市政工程设计研究总院

【摘要】 通过(Box-Behnken)响应面法,以硅烷偶联剂改性过的蒙脱土、苯乙烯-丁二烯-苯乙烯(SBS)和高黏剂(HVA)各自的掺量作为影响因素,以沥青3大指标、170℃布氏黏度为评价标准建立模型,确定3种材料在沥青中的最佳掺量。结果表明,5%SBS、9%HVA和8%的改性蒙脱土复配高黏改性沥青性能最好,其针入度、延度、软化点、170℃布氏黏度分别为4.52 mm、42.9 cm、86.1℃、2.371 Pa·s;相比于基质沥青和TPS高黏改性沥青,改性蒙脱土的加入大幅提高了沥青的高温性能与抗车辙能力,沥青黏度有着显著提升;振动峰的消失表明硅烷偶联剂对蒙脱土改性有化学反应。

【Abstract】 Using the Box-Behnken’s response surface method and taking the dosages of silane-coupling-agent-modified montmorillonite, SBS, and high viscosity agent(HVA) as influence factors for asphalt, a model was established to determine the optimal dosages of three types of raw materials in the asphalt based on the Brinell viscosity at 170 ℃ as an evaluation criterion. The results indicated that the high-viscosity-modified asphalt containing 5 wt% SBS, 9 wt% HVA, and 8 wt% modified montmorillonite exhibited the best performance, and its penetration, ductility, softening point, and Brinell’s viscosity at 170 ℃ were determined to be 4. 52 mm, 42. 9 cm, 86. 1 ℃, and 2. 371 Pa·s, respectively. Dynamic shear and Brinell’s viscosity tests show that, compared to the pristine asphalt and the high-viscosity-modified asphalt TPS, the addition of modified montmorillonite greatly improved the high-temperature performance and rutting resistance of asphalt, resulting in a significant improvement in the viscosity. The functional groups were analyzed by Fourier-transmission infrared spectroscopy. The disappearance of the vibration peaks indicated that the silane coupling agent involved a chemical reaction with montmorillonite in the modification process.

【基金】 天津市交通运输科技计划项目(2022-18);天津市自然科学基金资助项目(18JCTPJC54200)
  • 【文献出处】 中国塑料 ,China Plastics , 编辑部邮箱 ,2024年03期
  • 【分类号】U414
  • 【下载频次】95
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