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基于对醌醇的芳烃与并环化合物的多样性合成(英文)

Diverse transformations from p-quinols for the synthesis of arenes and fused cyclic compounds

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【作者】 智俊生; 郑百卉; 任宝平; HISASHI Shimakoshi; 李亦菲; 刘群; 潘秀梅; 潘玲;

【Author】 ZHI Junsheng;ZHENG Baihui;REN Baoping;HISASHI Shimakoshi;LI Yifei;LIU Qun;PAN Xiumei;PAN Ling;Department of Chemistry,Northeast Normal University;Department of Chemistry and Biochemistry,Graduate School of Engineering,Kyushu University;

【通讯作者】 潘玲;

【机构】 东北师范大学化学学院; Department of Chemistry and Biochemistry,Graduate School of Engineering,Kyushu University;

【摘要】 对醌醇是一类重要的2,5-环己二烯酮化合物,广泛应用于有机合成、药物化学和材料科学等领域。本文总结了从易得对醌醇出发的多取代芳烃和并环化合物的多样性合成,并对所涉及反应机理和反应的关键驱动力进行了讨论。

【Abstract】 Para-quinols(p-quinols) are a kind of cyclohexa-2,5-dienones, and are widely used as active synthons in organic synthesis, medicinal chemistry and materials science. Herein, the efficient synthesis of poly-substituted arenes and fused cyclic compounds from p-quinols has been summarized. The mechanisms and the key driving force of these efficient transformations have been discussed.

【关键词】 对醌醇; 合成; 芳烃; 并环; 芳构化; 加成;
【Key words】 quinols; synthesis; arenes; fused cycle; aromatization; addition;
【基金】 supported by the Department of Science and Technology of Jilin Province (20220402046GH, 20220101066JC)
  • 【文献出处】 分子科学学报 ,Journal of Molecular Science , 编辑部邮箱 ,2024年06期
  • 【分类号】O621.25
  • 【下载频次】6
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