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超高W含量NiW中/重合金热加工行为研究

Hot Workability of NiW Medium/Heavy Alloys with Ultra-high W Content

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【作者】 曹国鑫董建新张胜姚志浩解国良聂志华马腾飞付宝全

【Author】 Cao Guoxin;Dong Jianxin;Zhang Sheng;Yao Zhihao;Xie Guoliang;Nie Zhihua;Ma Tengfei;Fu Baoquan;School of Materials Science and Engineering,University of Science and Technology Beijing;Xi’an Superalloy Technology Co.,Ltd;School of Materials Science and Engineering,Beijing Institute of Technology;Key Laboratory of Air-driven Equipment Technology of Zhejiang Province,Quzhou University;

【通讯作者】 董建新;

【机构】 北京科技大学材料科学与工程学院西安聚能高温合金材料科技有限公司北京理工大学材料学院衢州学院浙江省空气动力装备技术重点实验室

【摘要】 采用Gleeble-1500D研究了Ni-42W-10Co-1Mo(质量分数,%)中/重合金(MHA)在1150~1300℃和应变速率0.001~1 s-1下流变行为和微观组织演化规律。结果表明,该合金初始组织由面心立方基体和初生σ相构成。流变应力对变形温度和应变速率敏感,在较高应变速率1s-1下,应力-应变曲线呈现出典型的动态回复软化特征,而在较低应变速率0.1~0.001 s-1下变形应力-应变曲线呈现出典型动态再结晶软化特征。基于应力-应变曲线建立了Arrhenius本构方程,并计算得到Ni-42W-10Co-1Mo合金热变形激活能为446.2 kJ/mol。基于动态材料模型构建该合金热加工图,发现在1300℃高应变速率下存在失稳区。通过微观组织分析,揭示其动态再结晶机制主要为不连续动态再结晶,σ相促进动态再结晶优先在其周围形核。最终优化获得了Ni-42W-10Co-1Mo合金最佳的热加工窗口:1250~1300℃,应变速率0.1~0.01 s-1

【Abstract】 The flow behavior and microstructural evolution of a high-density Ni-42W-10Co-1Mo(wt%) alloy were investigated at 1150-1300 ℃ under strain rates of 0.001-1 s-1 using a Gleeble-1500D. The results show that the initial microstructure is composed of face-centered cubic matrix and σ phase. The flow stress is sensitive to the deformation temperature and strain rate, and the stress-strain curve shows typical dynamic revertive softening characteristics when deformed at 1 s-1, while typical dynamic recrystallization softening characteristics are observed when deformed at 0.1-0.001 s-1. The Arrhenius equation was established based on the stress-strain curves, and the hot deformation activation energy of the Ni-42W-10Co-1Mo alloy was calculated to be 446.2 kJ/mol. The thermal processing map was constructed based on the dynamic material model to evaluate the thermal processing performance, and the instable zone was located at 1300 ℃under high strain rate. The deformation microstructural evolution reveals that the dynamic recrystallization mechanism is discontinuous dynamic recrystallization, which preferentially nucleates around the σ phase. Finally, the optimized hot working window for Ni-42W-10Co-1Mo alloy was obtained at 1250-1300 ℃ under strain rate of 0.1-0.01 s-1.

【基金】 国家自然科学基金(51771016)
  • 【文献出处】 稀有金属材料与工程 ,Rare Metal Materials and Engineering , 编辑部邮箱 ,2024年05期
  • 【分类号】TG139
  • 【下载频次】54
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