Effect of Post-Annealing on Structural and Electrical Properties of ZnO:In Films

【摘要】 Indium-doped ZnO（ZnO:In） films are deposited on quartz substrates by rf magnetron sputtering. The effects of post-annealing on structural, electrical, optical and Raman properties are investigated by x-ray diffraction,Raman scattering, Hall measurement and first-principles calculation. The results indicate that all of the ZnO:In films have excellent crystallinity with a preferred ZnO（002） orientation. It is found that the incorporation of In can dramatically increase the intensity of the 274 cm^-1 Raman mode. However, both post-annealing treatment and increasing O₂ partial pressure in the process of preparing thin films can reduce the intensity of the 274 cm^-1 mode or even eliminate it, and relax compressive stress of the ZnO:In film judged by analyzing the shifts of the（002） Bragg peaks and E₂（high） mode. Finally, the origin of the 274 cm^-1 mode is inferred to be the vibration of Zn interstitial（Zni） defects, which play a crucial role in the high electron concentration and low resistivity of ZnO:In films annealed in an appropriate temperature range（450–600℃）.更多还原

【Abstract】 Indium-doped ZnO（ZnO:In） films are deposited on quartz substrates by rf magnetron sputtering. The effects of post-annealing on structural, electrical, optical and Raman properties are investigated by x-ray diffraction,Raman scattering, Hall measurement and first-principles calculation. The results indicate that all of the ZnO:In films have excellent crystallinity with a preferred ZnO（002） orientation. It is found that the incorporation of In can dramatically increase the intensity of the 274 cm^-1 Raman mode. However, both post-annealing treatment and increasing O₂ partial pressure in the process of preparing thin films can reduce the intensity of the 274 cm^-1 mode or even eliminate it, and relax compressive stress of the ZnO:In film judged by analyzing the shifts of the（002） Bragg peaks and E₂（high） mode. Finally, the origin of the 274 cm^-1 mode is inferred to be the vibration of Zn interstitial（Zni） defects, which play a crucial role in the high electron concentration and low resistivity of ZnO:In films annealed in an appropriate temperature range（450–600℃）.更多还原