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Cu-Be-Co-Zr合金时效析出动力学(英文)

Phase Transformation Kinetics of Cu-Be-Co-Zr Alloy During Aging Treatment

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【作者】 周延军宋克兴米绪军刘勇杨少丹李周

【Author】 Zhou Yanjun;Song Kexing;Mi Xujun;Liu Yong;Yang Shaodan;Li Zhou;Henan University of Science and Technology;General Research Institute for Nonferrous Metals;Central South University;

【机构】 河南科技大学北京有色金属研究总院中南大学

【摘要】 研究了Cu-Be-Co-Zr合金480℃恒温时效条件下的时效析出动力学。根据导电率与析出相体积分数的关系,计算了Cu-Be-Co-Z合金不同时效时间(0,30,60,120,180,240,360,480,600 min)对应的析出相转变比率,建立了Cu-Be-Co-Zr合金480℃时效条件下的析出相变动力学方程和导电率方程,并在此基础上绘制了等温转变动力学S曲线;采用固态热分解反应机理的积分方程,揭示了Cu-Be-Co-Zr合金时效析出转变机制为受扩散控制的反应机理。

【Abstract】 The phase transformation kinetics of Cu-Be-Co-Zr alloy during aging treatment was investigated. Based on the relationship between electrical conductivity and volume fraction of precipitates, the phase transformation ratios of Cu-Be-Co-Zr alloy aged at 480 ℃ for different holding time(0, 30, 60, 120, 180, 240, 360, 480, and 600 min) were calculated. The kinetics equation of phase transformation and the electrical conductivity equation were derived. The isothermal transformation kinetics S-curves of Cu-Be-Co-Zr alloy was drawn. By the integral equation of solid thermal decomposition reaction mechanism, the phase transformation mechanism of Cu-Be-Co-Zr alloy is controlled by three dimensions of diffusion.

【基金】 National Key Research and Development Program of China(2016YFB0301400);State Key Program of National Natural Science Foundation of China(U1502274);Innovation Scientists and Technicians Troop Construction Projects of Henan Province(C20150014);Program for Innovation Research Team(in Science and Technology)in University of Henan Province(14IRTSTHN007)
  • 【文献出处】 稀有金属材料与工程 ,Rare Metal Materials and Engineering , 编辑部邮箱 ,2018年04期
  • 【分类号】TG146.11
  • 【被引频次】3
  • 【下载频次】163
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