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一维Fe2O3/α-MoO3异质结的制备及其可见光光催化性能

Preparation and Visible-light Photocatalytic Properties of One Dimensional Fe2O3/ α-MoO3 Heterostructures

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【作者】 甄延忠王杰王丹军付峰李静薛岗林

【Author】 ZHEN Yan-zhong;WANG Jie;WANG Dan-jun;FU Feng;LI Jing;XUE Gang-lin;Shaanxi Key Laboratory of Chemical Reaction Engineering,Yanan University;Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education,College of Chemistry and Materials Science,Northwest University;

【机构】 延安大学陕西省化学反应工程重点实验室西北大学化学与材料科学学院合成与天然功能分子化学教育部重点实验室

【摘要】 利用沉积法获得了一维Fe2O3/α-MoO3异质结光催化剂,通过XRD、SEM-EDS、STEM、XPS、UV-Vis-DRS等测试手段对其组成、形貌、光吸收性质进行了表征,同时在可见光区测试了光催化氧化降解罗丹明B溶液的性能。测试结果表明,Fe2O3修饰一维α-MoO3纳米带可将其光响应扩展至可见光区域,提高光催化性能。1wt%Fe2O3/α-MoO3异质结作为光催化剂时,光照40 min后罗丹明B降解率可达到99%,分别是纯α-MoO3纳米带和纯Fe2O3的光催化活性的3.8倍和26倍。

【Abstract】 One Dimension(1D) heterostructure photocatalyst Fe2O3/ α-MoO3 was fabricated by depositional method, which its composition, morphology and photo-adsorption properties of were characterized by XRD、SEM-EDS、STEM、XPS、UV-Vis-DRS,as so as,the performance of photocatalytic degradation Rh B was also explored. The test results show that the Fe2O3 modification not only broaden the absorption spectrum of α-MoO3 nanobelt to the visible light region,but also increase the photocatalytic activity. The optimum photocatalytic activity of MoO3 at Fe2O3weight content of 1% could reach 99%after visible light irradiation 40 minutes,which is almost 3. 8 and 26 times as high as that of the pure MoO3 nanobelts and Fe2O3.

【关键词】 Fe2O3α-MoO3异质结可见光催化剂
【Key words】 Fe2O3α-MoO3heterostructurevisible-light photocatalysis
【基金】 国家自然科学基金(21406188);陕西省科技攻关项目(2015GY174);陕西省教育厅自然科学基金(14Jk1831);科技成果转化与推广计划项目(2016CGZH-12-01)择优支持
  • 【文献出处】 人工晶体学报 ,Journal of Synthetic Crystals , 编辑部邮箱 ,2017年01期
  • 【分类号】O643.36
  • 【被引频次】9
  • 【下载频次】279
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