【摘要】 利用混合溶剂热方法制备了一种基于一维配位聚合物Cd（pdon）（oba）·H₂O（pdon=1,10-菲罗啉-5,6二酮,H₂oba=4,4′-氧二苯甲酸）的三维超分子.采用单晶X射线衍射对其进行了表征.结果表明:该配合物属于单斜晶系,C2/c空间群;晶胞参数a=2.025 77（9）nm,b=1.756 28（8）nm,c=1.437 96（7）nm,Z=8,V=4.610 8（4）nm3,R=0.031 2,wR=0.081 3.研究表明,该固态化合物在室温下具有蓝绿色荧光性质,并对亚甲基蓝具有光催化降解活性.更多还原

【Abstract】 A new 3 Dsupramolecular compound based on 1 Dcoordination polymers Cd（pdon）（oba）·H₂O[4,4′-H2 oba=4,4′-oxybis（benzoic acid）,pdon=1,10-phenanthroline-5,6-dione]has been prepared in mixed solvent condition.Single-crystal X-ray diffraction analysis shows the compound crystallized in the monoclinic,space group C2/c,a=2.025 77（9）nm,b=1.756 28（8）nm,c=1.437 96（7）nm,Z=8,V=4.610 8（4）nm3,R=0.031 2,wR=0.081 3.Moreover,the fluorescent property and the photocatalytic activity for the degradation of methylene blue of the title compound were investigated.更多还原