White Light Emission from ZnS:Mn Thin Films Deposited on GaN Substrates by Pulsed Laser Deposition

【摘要】 ZnS:Mn thin films are grown on GaN substrates by pulsed laser deposition.The structure,morphology and optical properties are investigated by x-ray diffraction,scanning electron microscopy and photoluminescence(PL).The obtained ZnS:Mn thin films are grown in preferred orientation along β-ZnS(111) direction corresponding to crystalline structure of cubic phase.The deposition temperature has an obvious effect on the structure,surface morphology and optical properties of ZnS:Mn thin films.PL measurements show that there are two emission bands located at 440 nm and 595 nm when the films are deposited at temperatures from 100℃ to 500℃.The relative integrated intensity of the blue emission and orange-red emission is determined by the deposition conditions.At the proper deposition temperature of 300℃,the color coordinate is closest to(0.33,0.33).The ZnS:Mn films on GaN substrates can exhibit white fight emission.更多还原

【Abstract】 ZnS:Mn thin films are grown on GaN substrates by pulsed laser deposition.The structure,morphology and optical properties are investigated by x-ray diffraction,scanning electron microscopy and photoluminescence(PL).The obtained ZnS:Mn thin films are grown in preferred orientation along β-ZnS(111) direction corresponding to crystalline structure of cubic phase.The deposition temperature has an obvious effect on the structure,surface morphology and optical properties of ZnS:Mn thin films.PL measurements show that there are two emission bands located at 440 nm and 595 nm when the films are deposited at temperatures from 100℃ to 500℃.The relative integrated intensity of the blue emission and orange-red emission is determined by the deposition conditions.At the proper deposition temperature of 300℃,the color coordinate is closest to(0.33,0.33).The ZnS:Mn films on GaN substrates can exhibit white fight emission.更多还原