【摘要】 含{CuCN}的聚合物具有新颖的结构,在气体吸附、催化剂、荧光材料和抗肿瘤等方面具有潜在的应用,但其合成的原料多为剧毒KCN,限制了其深入研究,探索使用低毒反应物合成其聚合物,是材料学者、化学工作者关注之一,因此,利用水热合成技术,选择低毒K4[Fe(CN)6]为反应物,通过调节反应物浓度、控制反应温度、反应时间等方法合成了一种以{CuCN}为基本骨架的配位聚合物,通过元素分析、IR和X-射线衍射对晶体结构进行了表征,对化合物的性质进行了初步研究.更多还原

【Abstract】 Coordination ploymers containing { CuCN} with novel structure have potential application in gas adsorption,catalyst,fluorescent material and anti- tumor. However the raw materia are often KCN,a kind of toxic material,which limits the further research. The exploration of the use of lower toxic reaction material for the synthesis of polymer is the attention between the material and chemist scientists. Under hydrothermal condition,nine coordination ploymers based on { CuCN} building blocks were prepared with K4[Fe( CN)6]by adjusting the reaction concerntration,the control of reaction temperature and time,which are characterized by elemental analysis,ICP Fluorescence property and UV properties更多还原