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纳米结构氧化锰/碳复合材料的制备及其超级电容器性能研究(英文)
Hydrothermal Synthesis of Nanostructured Manganese Oxide/Carbon Composites as Electrochemical Capacitors Electrodes
【摘要】 通过水热法在150℃保温6h和9h制备了纳米带状氧化锰与碳复合材料(MnO(OH)/C)。表征和分析结果表明,MnO(OH)为纳米带状结构,直径为48nm,长度为几微米,碳为近似球形结构,直径约为50nm。以1.0mol/L的Na2SO4溶液为电解液,以所制备的MnO(OH)/C复合材料为工作电极,对其超级电容器循环伏安和恒流充放电性能进行了分析。结果表明,在0.2A/g的电流密度下,电极材料的比电容可达到116.3F/g,当电流密度增加至2.0A/g时,其比电容保持率可达82.6%。
【Abstract】 Nanoribbon-like manganese oxide(MnO(OH))/carbon composites were synthesized with a hydrothermal method at 150 °C for 6 h and 9 h. The MnO(OH) is in diameters of 48 nm and lengths up to several micrometers. The carbon particulates are of sphere-like morphological structures with diameters of 50 nm. With the reaction time increasing from 6 h to 9 h, the shapes of the carbon particulates turn to more regular. The cycle voltammetry and galvanostatic charge-discharge performances of the composites were analyzed with the composites as the working electrodes and nickel foam as the counter electrodes in 1.0 mol/L Na2SO4 electrolytes. The results show that a specific capacitance of 116.3 F/g can be obtained at a current density of 0.2 A/g and a retention of 82.6% is observed when current density increases to 2.0 A/g.
- 【文献出处】 稀有金属材料与工程 ,Rare Metal Materials and Engineering , 编辑部邮箱 ,2016年S1期
- 【分类号】TB332
- 【被引频次】1
- 【下载频次】180