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压蒸条件下钢渣的碳化过程

Study on Carbonization Process of Steel Slag Under Pressure Steam Conditions

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【作者】 郜效娇卢豹蒋伟丽张峰姜瑞雨许宁陶泽天方永浩刘稼祥曹月斌张勤芳侯贵华

【Author】 GAO Xiaojiao;LU Bao;JIANG Weili;ZHANG Feng;JIANG Ruiyu;XU Ning;TAO Zetian;FANG Yonghao;LIU Jiaxiang;CAO Yuebin;ZHANG Qinfang;HOU Guihua;School of Materials Science and Engineering,Changzhou University;Key Laboratory for Advanced Technology in Environmental Protection of Jiangsu Province,Yancheng Institute of Technology;School of Mechanics and Materials,Hohai Unversity;School of Materials Science and Engineering,Beijing University of Chemical Technology;

【机构】 常州大学材料科学与工程学院盐城工学院江苏省新型环保重点实验室河海大学力学与材料学院北京化工大学材料科学与工程学院

【摘要】 将钢渣压制成一定形状的试块,分别在60℃、90℃及120℃下采用CO2对试块进行了碳化处理。对碳化后试块的质量、体积、抗压强度的变化进行了测试。采用X射线能谱仪(XRD)、热重-差热分析仪(TG-DSC)分析了碳化过程中的物相变化。用扫描电子显微镜(SEM)观察了碳化后产物的微观形貌。研究结果表明,在60℃、90℃、120℃碳化温度下碳化7d后,试块的质量分别增加15.30%、17.48%、23.84%;试块的体积分别增加5.9%、6.5%、11.44%;试块的抗压强度分别达到32.87 MPa、39.62 MPa、42.38 MPa。钢渣碳化后产物主要为CaCO3。从碳化后试块的力学强度和节能两方面综合考虑,碳化的最佳温度为90℃。

【Abstract】 Steel slag was pressed into pellets with a certain shape,and then they were carbonized using CO2 at temperature 60 ℃,90 ℃ and 120 ℃ respectively.Change of mass,volume and mechanical strength after carbonization were tested.Structural changes of steel slag during carbonization were characterized with XRD and TG-DSC.Morphologies of the carbonized steel slag were characterized with SEM.The results indicated that after carbonized at60℃,90℃and 120℃for 7days,the mass of steel slag increased by 15.30%,17.48%and 23.84%;the volume of steel slag increased by 5.9%,6.5% and 11.44%;and the mechanical strength of steel slag increased to 32.87 MPa,39.62 MPa and 42.38 MPa,respectively.The main phase of carbonized steel slag was CaCO3.Considering mechanical strength and energy saving,the optimum carbonization temperature for steel slag was 90 ℃.

【基金】 国家科技支撑计划(2013BAC13B01-03);江苏省新型环保重点实验室及江苏省“生态建材与环保装备”协同创新中心联合基金(CP201503)
  • 【文献出处】 材料导报 ,Materials Review , 编辑部邮箱 ,2016年04期
  • 【分类号】TU521.4
  • 【被引频次】12
  • 【下载频次】423
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