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水固比对Ca3Si2O7矿物碳化的影响

The Influence of Water Solid Ratio to the Carbonization of Rankinite

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【作者】 卢豹郜效娇蒋伟丽张峰姜瑞雨许宁陶泽天曹月斌张勤芳刘小艳方永浩侯贵华

【Author】 LU Bao;GAO Xiaojiao;JIANG Weili;ZHANG Feng;JIANG Ruiyu;XU Ning;TAO Zetian;CAO Yuebin;ZHANG Qinfang;LIU Xiaoyan;FANG Yonghao;HOU Guihua;College of Mechanics and Materials,Hohai University;Key Laboratory for Advanced Technology in Environmental Protection of Jiangsu Province,Yancheng Institute of Technology;

【机构】 河海大学力学与材料学院盐城工学院江苏省环保重点实验室

【摘要】 以Ca3Si2O7(C3S2)矿物和CO2为反应物,以水为反应介质,研究了不同水固比条件下C3S2的碳化过程,测定了碳化过程中的质量、体积及抗压强度变化,用X射线衍射仪(XRD)、扫描电子显微镜(SEM)、同步热分析仪(TG-DSC)等测试手段,研究不同水固比条件下试样的物相与形貌变化,结果表明水固比显著影响C3S2的碳化速率,研究发现最佳掺水量为14%,在此条件下C3S2矿物碳化3d的增重率为13.5%、抗压强度为33.6 MPa。

【Abstract】 With rankinite(C3S2)mineral and CO2 as the reactant,water as reaction medium,rankinite carbonization process was studied under the condition of different water cement ratio,at the same time,the quality and volume of carbonization process was measured as same as compressive strength.Through X-ray diffractometer(XRD),scanning electron microscope(SEM),differential thermal scanning calorimetry analyzer(TG and DSC)test means,phase morphology changes were studied under the condition of different water cement ratio.Results showed that water solid ratio significantly influences the carbonization rate of rankinite.The best mixing water was 14%,under which condition,the carbide weight gain rate of rankinite mineral was 13.5%,and the compressive strength was 33.6 MPa after 3days.

【关键词】 C3S2矿物水固比碳化
【Key words】 rankinitewater solid ratiocarbonization
【基金】 国家科技支撑计划(2013BAC13B01-03);江苏省新型环保重点实验室及江苏省“生态建材与环保装备”协同创新中心联合基金(CP201503)
  • 【文献出处】 材料导报 ,Materials Review , 编辑部邮箱 ,2016年02期
  • 【分类号】TQ172.4
  • 【被引频次】10
  • 【下载频次】232
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