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紫外光固化水性聚氨酯丙烯酸酯的合成与应用研究

Synthesis and application of UV-curable waterborne polyurethane acrylate resin

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【作者】 王朝栋虞鑫海刘万章陈吉伟

【Author】 WANG Chao-dong;YU Xin-hai;LIU Wan-zhang;CHEN Ji-wei;College of Chemical and Biological Engineering, Donghua University;Zhejiang Golden Roc Chemical Co.,Ltd.;

【机构】 东华大学化学化工与生物工程学院浙江金鹏化工股份有限公司

【摘要】 采用丙酮法,以异佛尔酮二异氰酸酯(IPDI)与聚酯/聚醚混合多元醇、二羟甲基丙酸(DMPA)、甲基丙烯酸羟乙酯(HEMA)为原料合成紫外光固化水性聚氨酯预聚体,经中和剂中和后制备固含量为30%的聚氨酯乳液。探究了紫外光固化聚氨酯乳液的性能以及光引发剂类型、用量以及中和剂对其光固化速率的影响。

【Abstract】 The title UV-curable waterborne PUA prepolymers were synthesized by acetone process using IPDI,Polyester/Polyether polyols,DMPA and HEMA as main materials. The solid content of the polyurethane emulsion was 30% after the neutralization. The properties of UV-curable waterborne PUA emulsion and the influence of type and amount of photoinitiator, neutralizing agents and drying time on its UV-curing rate were explored.

  • 【文献出处】 粘接 ,Adhesion , 编辑部邮箱 ,2015年05期
  • 【分类号】TQ630.1
  • 【被引频次】13
  • 【下载频次】298
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