【摘要】 以对叔丁基杯〔4〕芳烃为原料,对其上沿的叔丁基进行修饰,经不同的合成路线,利用羟基保护、取代、去叔丁基、硝化以及还原合成了尚未报道的新型氮杂杯〔4〕芳烃衍生物。其结构经1 H NMR,13C NMR和GC-MS表征。更多还原

【Abstract】 The target compounds azacalix〔4〕arene which has not been reported,were synthesized using calix〔4〕arene as starting material by several steps reaction including hydroxyl protection,substitution,retro-Friedel-Crafts,nitration and reduction.The structure of these compounds were characterized by 1 HNMR,13 CNMR and GC-MS.The results showed that these compounds exhibited good complex effects with some heavy metals.更多还原