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中和法调节硫磺冶炼废渣pH值的试验研究

Research on p H Adjustment of Sulfur Smelting Slag with Neutralization Method

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【作者】 和丽萍范泽文王瑞波常普徐西蒙李灿婷郑绍武

【Author】 HE Liping;FAN Zewen;WANG Ruibo;CHANG Pu;XU Ximeng;LI Canting;ZHENG Shaowu;Yunnan Institute of Environmental Sciences;Zhenxiong Environmental Research and Monitoring Station;Chemical and Biological Technology, Yunnan University of Nationalities;

【机构】 云南省环境科学研究院镇雄县环境科研监测站云南民族大学化学与生物技术学院

【摘要】 土法冶炼硫磺废渣浸出液中主要超标因子为p H值,采用生石灰与土法冶炼硫磺废渣进行中和,可将其浸出液由呈强酸性变成中性,废渣属性由Ⅱ类一般工业固体废物变为Ⅰ类一般工业固体废物。试验结果表明,生石灰投加比例约为0.5%,浸出液p H值从3.0~4.8之间调整为6~9时,浸出液中的铁、锰、铜、砷等多种重金属浓度可明显下降,降幅可达90%左右。经中和后的废渣,其环境安全风险明显降低,从而可减少废渣处置场防渗处理工艺、工程投资,降低处置场运营管理难度及风险。

【Abstract】 As the main exceeded factor of the sulfur smelting slag leachate, p H value can be adjusted to neutral level through neutralization with quicklime thus turning the slag from I class industrial solid waste to II class industrial solid waste. The experimental results suggest that: With 0.5% quicklime added, adjusting p H value from 3.0~4.8 to 6~9, the heavy metals concentrations(such as iron, manganese, copper, arsenic, etc.) decline of the leachate can be up to 90%.The environmental safety risk of waste residue after neutralization have significant decrease, thus reducing the engineering investment and operation difficulties of waste disposal sites.

【关键词】 硫磺冶炼废渣生石灰中和浸出液pH值
【Key words】 sulfur smelting slagquicklimeneutralizationleachatep H values
  • 【文献出处】 环境科学与技术 ,Environmental Science & Technology , 编辑部邮箱 ,2014年S2期
  • 【分类号】X756
  • 【下载频次】71
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