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纳米银粉对锌负极电化学性能的影响
Effect of nanosilver on the electrochemical performance for zinc anode
【摘要】 以葡萄糖为还原剂、聚乙烯吡咯烷酮(PVP)为分散剂,在碱性条件下化学还原硝酸银溶液制备纳米银粉,再通过共沉积掺入到锌负极中,考察制备的锌镍电池的充放电、倍率和循环性能。锌负极中掺入银后,氢气的析出受到抑制,放电电压和容量都得到提高。掺银0.07%的锌负极以1 C在2.0~1.3 V循环30次,放电容量为最高值的46.6%。
【Abstract】 Nanosilver powder was obtained by reducing AgNO3 solution in alkaline condition with glucose as reductant.PVP as dispersant,then was doped into Zn anode by codeposition,the charge-discharge,rate and cycle performance of prepared Ni-Zn battery was investigated.After doping Ag,hydrogen evolution was suppressed,the discharge voltage and capacity was elevated.After cycle30 times at 1 C in 2.0 1.3 V,the discharge capacity of Zn anode doped with 0.07% Ag was 46.6% of the maximum value.
【关键词】 纳米银;
锌负极;
锌镍二次电池;
电化学性能;
【Key words】 nanosilver; zinc anode; Ni/Zn secondary battery; electrochemical performance;
【Key words】 nanosilver; zinc anode; Ni/Zn secondary battery; electrochemical performance;
【基金】 河南省自然科学基金(132102210161)
- 【文献出处】 电池 ,Battery Bimonthly , 编辑部邮箱 ,2014年04期
- 【分类号】TM912.9
- 【被引频次】2
- 【下载频次】75