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钯催化的脂肪醇的芳基化反应研究进展
Recent Developments on Pd-Catalyzed Arylations of Aliphatic Alcohols
【摘要】 烷基芳基醚结构广泛存在于天然和人工药物中,Pd催化的脂肪醇的芳基化反应是合成这类化合物的重要方法之一.重点综述了成功运用于脂肪醇的C—O偶联反应的四大类配体,对C—O偶联反应的应用进行了概述,对该类反应研究前景也进行了展望.
【Abstract】 Aromatic ethers of aliphatic alcohols represent an important structural motif in many naturally occurring and medicinally relevant compounds. Palladium-catalyzed aliphatic alcohol arylation is a kind of important methods to access them.This review focuses on four types of phosphorus ligands successfully employed in C—O cross coupling reactions of aliphatic alcohols. The applications of C—O cross coupling reactions are summarized and the reaction potential research areas are also discussed.
【关键词】 钯催化;
烷基芳基醚;
C—O偶联反应;
膦配体;
【Key words】 palladium catalysis; alkyl aryl ether; C—O cross-coupling; phosphorus ligand;
【Key words】 palladium catalysis; alkyl aryl ether; C—O cross-coupling; phosphorus ligand;
【基金】 国家自然科学基金(No.21202090);宁波市科技创新团队(No.2011B82002);浙江省自然科学基金(No.LY12B02001);宁波市自然科学基金(Nos.2011A610123,2012A610123)资助项目~~
- 【文献出处】 有机化学 ,Chinese Journal of Organic Chemistry , 编辑部邮箱 ,2013年08期
- 【分类号】O643.32
- 【被引频次】5
- 【下载频次】168