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活化黏土对羧甲基壳聚糖控制吡虫啉释放的强化作用

Improvement by Activated Clay on the Controlled Release of Imidacloprid with Carboxymethyl Chitosan

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【作者】 钟佳薇吕金红李建法何霞朱亚媛

【Author】 ZHONG Jia-wei,LYU Jin-hong,LI Jian-fa,HE Xia,ZHU Ya-yuan(Department of Chemistry,Shaoxing College of Arts and Science,Shaoxing 312000,Zhejiang,China)

【机构】 绍兴文理学院化学系

【摘要】 [目的]以活化黏土为吸附剂,与羧甲基壳聚糖复合制备颗粒状控制释放制剂,以延缓吡虫啉释放、提高药效并控制其污染。[方法]分别采用水中释放实验、土壤表层淋出实验,考察颗粒制剂控制吡虫啉释放及抑制其淋溶的效果。[结果]颗粒制剂中吡虫啉在水中的半数释放时间(t50)延长至25.5 h,释放过程受费克扩散控制,9次淋洗后吡虫啉的累计淋出率仅为28.6%。[结论]活化黏土可以进一步延缓吡虫啉的释放,显著减少其对地下水的污染。

【Abstract】 Activated clay,as the sorbent,was used in combination with carboxymethyl chitosan to prepare the granular controlled release formulations,so as to extend the release of imidacloprid,enhance the efficacy and control its pollution.[Methods] The release experiments in water and leaching experiments through a thin soil layer were carried out to investigate the performance of the granular formulations on controlling the release and inhibiting the leaching of imidacloprid.[Results] The time taken for 50% imidacloprid to be released(t50) in water from the granular CRF was prolonged to 25.5 h,and the release was controlled by Fickian diffusion.After irrigation of 9 times,the cumulative ratio of imidacloprid leached accounted for only 28.6%.[Conclusions] The activated clay can further delay the release of imidacloprid,and reduce its pollution to groundwater.

【关键词】 农药壳聚糖黏土控制释放
【Key words】 pesticidechitosanclaycontrolled release
【基金】 浙江省公益性技术应用研究计划(2010C32086);浙江省大学生科技创新推广计划资助项目
  • 【文献出处】 农药 ,Agrochemicals , 编辑部邮箱 ,2013年04期
  • 【分类号】TQ450.1
  • 【下载频次】92
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