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有机改性凹凸棒石吸附活性艳蓝KN-R的动力学研究
Kinetics of Adsorption of Reactive Brilliant Blue KN-R onto Organic Modified Attapulgite
【摘要】 通过静态吸附实验方法,研究了有机改性凹凸棒石吸附活性艳蓝KN-R的动力学行为。研究结果表明:准二级动力学模型能很好地描述活性艳蓝KN-R在有机改性凹凸棒石上的动力学行为,平衡吸附量q2随着KN-R初始浓度、振荡速度、温度的增加而增加。有机改性凹凸棒石吸附活性艳蓝KN-R主要是外表面吸附,吸附活化能为39.2kJ/mol,说明其为物理吸附、化学吸附综合作用的过程,其速率由化学过程与外扩散共同控制。
【Abstract】 By static adsorption experiments,the adsorption dynamics of organic modified attapulgite on reactive brilliant blue KN-R was studied.The results indicate that the adsorption of KN-R by organic modified attapulgite follows the pseudo-second order kinetic model.The amount of KN-R adsorbed at equilibrium(q2) increases with the increasing of initial mass concentration for KN-R,agitation speed and temperature.The results also show that KN-R is mainly adsorbed on the external surface of organic modified attapulgite,the adsorption activation energy is 39.2 kJ/mol.It means that the adsorption is a process combinated by physical and chemical adsorption,and the adsorption rate is controlled by not only chemical adsorption but also physical adsorption.
【Key words】 organic modification; attapulgite; absorption; reactive brilliant blue KN-R; kinetics;
- 【文献出处】 材料导报 ,Materials Review , 编辑部邮箱 ,2013年04期
- 【分类号】X703
- 【被引频次】3
- 【下载频次】118