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钴冰镍常压浸出工艺研究

Study on Atmospheric Pressure Leaching Process of Cobalt-nickel Matte

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【作者】 周雍茂胡宝磊

【Author】 ZHOU Yong-mao,HU Bao-lei (School of Metallurgical Science and Engineering,Central South University,Changsha 410083,China)

【机构】 中南大学冶金科学与工程学院

【摘要】 以镍转炉渣还原硫化熔炼得到的钴冰镍为原料,在常压下于硫酸体系中进行浸出,考察了硫酸浓度、液固比、浸出时间及浸出温度对钴冰镍中有价成分浸出率的影响。结果表明,液固比和硫酸浓度对钴、镍、铁的浸出率影响较大。当硫酸浓度为1.6mol/L、液固比5、浸出时间2.5h、浸出温度85℃时,铁浸出率达到69%,镍、钴浸出率分别控制在1%和5%以内,取得了很好的选择性浸出效果。

【Abstract】 The cobalt-nickel matte,a reduction product from nickel converter slag by vulcanization smelting,was atmospherically pressure leached at the sulfuric acid system.The effects of sulfuric acid concentration,ratio of liquid to solid(L/S),leaching time and temperature on leaching rate of valuable metals were investigated.The results show that L/S and sulfuric acid concentration have great influence on the leaching rate of cobalt,nickel and ferrum.The ferrum leaching rate reaches to 69%,nickel and cobalt leaching rate could be controlled below 1% and 5% respectively under the conditions including sulfuric acid concentration of 1.6 mol/L,L/S of 5,leaching time of 2.5 h,and leaching temperature of 85 ℃.A good selectivity leaching effect was obtained.

【关键词】 钴冰镍浸出硫酸选择性浸出
【Key words】 cobalt-nickel matteleachingsulfuric acidnickelcobaltferrumselectivity leaching
  • 【文献出处】 有色金属(冶炼部分) ,Nonferrous Metals(Extractive Metallurgy) , 编辑部邮箱 ,2012年08期
  • 【分类号】TF815
  • 【被引频次】7
  • 【下载频次】105
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