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MBR中胞外聚合物对混合液过滤性能的影响

Effect of Extracellular Polymeric Substances on Filtration Characteristics of Mixtures in MBR

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【作者】 曹占平赵连梅张宏伟张景丽

【Author】 CAO Zhan-ping1,ZHAO Lian-mei2,ZHANG Hong-wei1,ZHANG Jing-li2(1.Key Laboratory of Hollow Fiber Membrane Material and Membrane Process <Ministry of Education>,Tianjin Polytechnic University,Tianjin 300160,China;2.Department of Environmental and Municipal Engineering,Tianjin Institute of Urban Construction,Tianjin 300384,China)

【机构】 天津工业大学中空纤维膜材料与膜过程教育部重点实验室天津城市建设学院环境与市政工程系

【摘要】 胞外聚合物(EPS)的含量和组成对混合液的特性和膜污染有着重要影响。采用SPSS统计分析法研究了紧密粘附胞外聚合物(TB)和松散附着胞外聚合物(LB)数量及其中蛋白质与多糖所占的比例对混合液特性及膜污染的影响。研究表明,随着EPS含量的增加,TB中蛋白质与多糖含量的比值减小,细菌存在状态由不稳定型(R型)向稳定型(S型)转变,SVI值增大;LB中蛋白质与多糖含量比值的增大,降低了混合液的Zeta电位,增加了混合液粘度和相对疏水性。上清液中悬浮固体颗粒的浓度、混合液的Zeta电位及相对疏水性是造成膜污染的主要因子,与膜污染阻力的皮尔逊系数分别为0.853、-0.818、0.832。

【Abstract】 The content and composition of extracellular polymeric substances(EPS) have an important influence on mixture characteristics and membrane fouling.The roles of TB-EPS and LB-EPS quantity and ratios of protein to polysaccharide,along with the effect of mixture characters on membrane fouling,were studied by SPSS statistical analysis.The results showed that the ratio of protein to polysaccharide in TB-EPS reduced with increasing EPS content.Consequently,bacteria transformed from unstable state(R) to stable state(S),and the sludge volume index(SVI) value increased.As the ratio of protein to polysaccharide in LB-EPS increased with increasing EPS content,the Zeta potential decreased,the mixture viscosity and relative hydrophobicity(RH) increased.The suspended solid concentration in the supernatant,Zeta potential and RH of the mixture affected membrane fouling the most.The corresponding Pearson’s correlation coefficients were 0.853,-0.818 and 0.832.

【基金】 国家自然科学基金资助项目(51078265);天津市自然科学基金资助项目(08JCZDJC24300)
  • 【文献出处】 中国给水排水 ,China Water & Wastewater , 编辑部邮箱 ,2012年11期
  • 【分类号】X703
  • 【被引频次】5
  • 【下载频次】166
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