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SiO2-Fe2O3-Cr2O3-MnO2高温红外辐射节能涂料的制备及应用

Preparation of high temperature infrared emissivity energy-saving coatings and its application

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【作者】 甄强马杰倪亮王亚丽李榕张中伟王金明

【Author】 ZHEN Qiang1,MA Jie1,NI Liang1,WANG Ya-li1,LI Rong1, ZHANG Zhong-wei2,WANG Jin-ming2(1.Nano Science and Technology Research Center,Shanghai University,Shanghai 200444,China; 2.Advanced Functional Composite Materials Technology National Key Laboratory,Beijing 100076,China)

【机构】 上海大学纳米科学与技术研究中心先进功能复合材料技术国防科技重点实验室

【摘要】 以SiO2、Fe2O3、Cr2O3、MnO2为原料按比例混合,经固相高温烧结制备成基体粉料,再与粘结剂混合球磨制备出高温红外辐射节能涂料。通过XRD、半球点测试仪、红外辐射测量仪、纳米粒度测试仪对材料的微观结构和理化性能进行了表征,采用热震法对涂层的抗热震性能进行了研究。研究结果表明,随着平均粒径的减小,合成的SiO2-Fe2O3-Cr2O3-MnO2体系全波段红外辐射率有明显增大的趋势。当平均粒径达到2μm左右时,涂料全波段红外辐射率最高达到0.93。涂料的最高使用温度达1400℃以上,涂层的抗热震性能良好。此外,在燃气梭式干燥窑上使用该高温红外辐射节能涂料后,降低能耗15%左右,抗老化性能优良,使用一年后辐射率仍在0.90以上。

【Abstract】 Using SiO2,Fe2O3,Cr2O3 and MnO2 powders as raw materials,the high temperature infrared emissivity energy-saving coatings were prepared by combined solid-state and milling method.The physical and chemical properties and microstructures of the obtained coatings were characterized by X-ray diffraction(XRD),hemisphere-point test,infrared radiation meter and nano-particle size meter.And their thermal shock resistance was also investigated by wind quenching-cracks determination method.The results showed that the prepared SiO2-Fe2O3-Cr2O3-MnO2 coating systems exhibited a infrared emissivity of 0.93 in the band of 1-22 μm and good thermal shock resistance,and their operating temperature cauld be up to 1400℃.Besides,when the prepared coatings were applied in gas shuttle drying kiln,the energy consumption of the kiln decreased by 15%.It can be expected that after one year of use,their infrared emissivity remains up to 0.90,which indicates that the coatings have excellent anti-aging performance.

【基金】 国家自然科学基金资助项目(51072112);上海市教育委员会重点学科建设资助项目(J50102);中国人民解放军总装备部武器装备预研基金资助项目(9140C5601010701,9140C5601010801);上海大学研究生创新基金资助项目(SHUCX112347)
  • 【文献出处】 功能材料 ,Journal of Functional Materials , 编辑部邮箱 ,2012年17期
  • 【分类号】TQ637
  • 【被引频次】11
  • 【下载频次】404
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