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纤维素-丝素复合膜的制备与表征

Preparation and characterization of cellulose/silk composite membrane

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【作者】 李娟何建新余燕平

【Author】 LI Juan1,HE Jian-xin1,2,YU Yan-ping1(1.Textile School,Donghua University,Shanghai 201620,China;2.Key Laboratory of Functional Textiles,The Education Department of Henan Province,Zhongyuan University of Technology,Zhengzhou 451191,China)

【机构】 东华大学纺织学院中原工学院河南省高等学校功能性纺织面料重点学科开放实验室

【摘要】 通过NaOH/尿素/硫脲/水新型溶剂溶解原生木浆纤维素得到纤维素溶液,并与丝素溶液混合制备纤维素-丝素复合膜。利用扫描电镜、红外光谱、X-射线衍射对复合材料的结构进行表征。SEM结果表明复合材料表面粗糙,比表面积较大,可以作为潜在的生物医用材料。IR和X-衍射结果表明再生纤维素与丝素分子之间存在着强烈的氢键作用,且二者相容性较好。

【Abstract】 The cellulose-silk fibroin composite film is prepared by mixing cellulose solution dissolved primary wood pulp in solution containing of NaOH/urea/thiourea/water and silk fibroin solution.The composite film is characterized by scanning electron microscope(SEM),Fourier transform infrared spectrometer(FT-IR),X-ray diffraction(XRD).SEM shows the surface of the composite is uniform and rough.The as-prepared composite film may be a potential biomedical material.The results of IR and XRD show that composite film is composed of cellulose and silk fibroin molecules and exists an interaction including hydrogen bond between the molecular of cellulose and silk fibroin.

【关键词】 纤维素丝素复合膜
【Key words】 cellulosesilkcomposite membrane
  • 【文献出处】 现代化工 ,Modern Chemical Industry , 编辑部邮箱 ,2011年S1期
  • 【分类号】TB383.2
  • 【被引频次】2
  • 【下载频次】150
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